Canonical ensemble: Difference between revisions
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''Classical'' Partition Function (one-component system): <math> Q_{NVT} </math> | ''Classical'' Partition Function (one-component system): <math> Q_{NVT} </math> | ||
<math> Q_{NVT} = \frac{V^N}{N! \Lambda^{3N} } \int d | <math> Q_{NVT} = \frac{V^N}{N! \Lambda^{3N} } \int d (R^*)^{3N} \exp \left[ - \beta U \left( V, (R^*)^{3N} \right) \right] </math> | ||
where: | |||
* <math> V </math> ... | |||
Revision as of 20:32, 19 February 2007
Canonical Ensemble:
Variables:
- Number of Particles,
- Volume,
- Temperature,
Partition Function
Classical Partition Function (one-component system):
![{\displaystyle Q_{NVT}={\frac {V^{N}}{N!\Lambda ^{3N}}}\int d(R^{*})^{3N}\exp \left[-\beta U\left(V,(R^{*})^{3N}\right)\right]}](https://wikimedia.org/api/rest_v1/media/math/render/svg/e0a1f8d5945d276d66dfbbee4f95a936b41a5a17)
where:
- ...