Square well model

The Square well model is given by

\Phi _{12}\left(r\right)=\left\{{\begin{array}{ccc}\infty &;&r<\sigma \\-\epsilon &;&\sigma \leq r<\lambda \sigma \\0&;&r\geq \lambda \sigma \end{array}}\right.

where $\Phi _{12}(r)$ is the intermolecular pair potential, $\epsilon$ is the well depth, Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle r} is the distance between site 1 and site 2 Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle r := |\mathbf{r}_1 - \mathbf{r}_2|} , σ is the hard diameter and λ > 1.

Equation of state

Main article: Equations of state for the square well model

Virial coefficients

Main article: Square well potential: virial coefficients

Liquid-vapour coexistence

Achille Giacometti, Giorgio Pastore and Fred Lado "Liquid-vapor coexistence in square-well fluids: an RHNC study", Molecular Physics 107 pp. 555-562 (2009)

Critical point

References

Square well model

Contents

Equation of state

Virial coefficients

Liquid-vapour coexistence

Critical point

References

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Square well model

Equation of state

Virial coefficients

Liquid-vapour coexistence

Critical point

References

Navigation menu

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