Cole equation of state

The Cole equation of state is the adiabatic version of the stiffened equation of state. (See Derivation, below.) It has the form

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p = B \left[ \left( \frac{\rho}{\rho_0} \right)^\gamma -1 \right]}

In it, $\rho _{0}$ is a reference density around which the density varies, Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \gamma} is the adiabatic index, and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle B} is a pressure parameter.

Usually, the equation is used to model a nearly incompressible system. In this case, the exponent is often set to a value of 7, and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle B} is large, in the following sense. The fluctuations of the density are related to the speed of sound as

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \frac{\delta \rho}{\rho} = \frac{v^2}{c^2} ,}

where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle v} is the largest velocity, and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle c} is the speed of sound (the ratio Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle v/c} is Mach's number). The speed of sound can be seen to be

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle c^2 = \frac{\gamma B}{\rho_0}. }

Therefore, if Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle B=100 \rho_0 v^2 / \gamma} , the relative density fluctuations will be about 0.01.

If the fluctuations in the density are indeed small, the equation of state may be approximated by the simpler:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p = B \gamma \left[ \frac{\rho-\rho_0}{\rho_0} \right]}

It is quite common that the name "Tait equation of state" is improperly used for this EOS. This perhaps stems for the classic text by Cole calling this equation a "modified Tait equation" (p. 39).

Derivation

Let us write the stiffened EOS as

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p+ p^* = (\gamma -1) e \rho = (\gamma -1) E / V ,}

where E is the internal energy. In an adiabatic process, the work is the only responsible of a change in internal energy. Hence the first law reads

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle dW= -p dV = dE .}

Taking differences on theEOS,

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle dE = \frac{1}{\gamma-1} [(p+p^*) dV + V dp ] , }

so that the first law can be simplified to

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle - (\gamma p + p^*) dV = V dp.}

This equation can be solved in the standard way, with the result

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle ( p + p^* / \gamma) V^\gamma = C ,}

where C is a constant of integration. This derivation closely follows the standard derivation of the adiabatic law of an ideal gas, and it reduces to it if Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p^* =0 } .

If the values of the thermodynamic variables are known at some reference state, we may write

$(p+p^{*}/\gamma )V^{\gamma }=(p_{0}+p^{*}/\gamma )V_{0}^{\gamma },$

which can be written as

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p = p_0 + ( p_0 + p^* / \gamma) ( (V_0/V)^\gamma - 1 ) . }

Going back to densities, instead of volumes,

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p = p_0 + ( p_0 + p^* / \gamma) ( (\rho/\rho_0)^\gamma - 1) . }

Comparing with the Cole EOS, we can readily identify

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle B = p^* / \gamma }

Moreover, the Cole EOS differs slightly, as it should read (as indeed does in e.g. the book by Courant)

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p = A \left( \frac{\rho}{\rho_0} \right)^\gamma - B ,}

with

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle A = p^* / \gamma + p_0 . }

This difference is negligible for liquids but for an ideal gas Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p^*=0} and there is a huge difference, B being zero and A being equal to the reference pressure.

Now, the speed of sound is given by

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle c^2=\frac{dp}{d\rho} }

with the derivative taken along an adiabatic line. This is precisely our case, and we readily obtain

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle c^2= ( p_0 + p^* / \gamma) \gamma /\rho_0 . }

From this expression a value of Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p^*} can be deduced. For water, $p^{*}\approx 23000$ bar, from which Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle B\approx 3000} bar. If the speed of sound is used in the EOS one obtains the rather elegant expression

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p = p_0 + ( \rho_0 c^2 / \gamma) ( (\rho/\rho_0)^\gamma - 1) . }