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The '''thermodynamic limit''' is reached as the number of particles (atoms or molecules) in a system approaches infinity. The thermodynamic behavior of a system is asymptotically approximated by the results of [[statistical mechanics]] as <math>N \rightarrow \infty</math>, and calculations using the various ensembles converge. | The '''thermodynamic limit''' is reached as the number of particles (atoms or molecules) in a system approaches infinity. The thermodynamic behavior of a system is asymptotically approximated by the results of [[statistical mechanics]] as <math>N \rightarrow \infty</math>, and calculations using the various ensembles converge. | ||
[[category: classical thermodynamics]] | [[category: classical thermodynamics]] | ||
[[category: statistical mechanics]] | [[category: statistical mechanics]] |