Strongly correlating liquids: Difference between revisions

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*[http://dx.doi.org/10.1063/1.3265955 Thomas B. Schrøder, Nicholas P. Bailey, Ulf R. Pedersen, Nicoletta Gnan, and Jeppe C. Dyre "Pressure-energy correlations in liquids. III. Statistical mechanics and thermodynamics of liquids with hidden scale invariance", Journal of Chemical Physics '''131''' 234503 (2009)]
*[http://dx.doi.org/10.1063/1.3265955 Thomas B. Schrøder, Nicholas P. Bailey, Ulf R. Pedersen, Nicoletta Gnan, and Jeppe C. Dyre "Pressure-energy correlations in liquids. III. Statistical mechanics and thermodynamics of liquids with hidden scale invariance", Journal of Chemical Physics '''131''' 234503 (2009)]


[[category:Complex systems]]
[[category: Classical thermodynamics]]
[[category: Statistical mechanics]]

Revision as of 14:26, 18 May 2011

Strongly correlating liquids are defined as those for whom where (Eq. 6 [1])

where represents fluctuations of the potential in the NVT ensemble and is the virial (see also Virial pressure).

Isomorphs

[2]

Lennard-Jones liquid

The liquid phase formed by the Lennard-Jones model is an example of a strongly correlating liquid[3].

References

Related reading