Square well model

The Square well model is given by

$\Phi \left(r\right)=\left\{{\begin{array}{ccc}\infty &;&r<\sigma \\-\epsilon &;&\sigma \leq r<\lambda \sigma \\0&;&r\geq \lambda \sigma \end{array}}\right.$

where $\Phi (r)$ is the intermolecular pair potential, r is the distance, σ is the hard diameter and λ > 1.

Equation of state

Main article: Equations of state for the square well model

Virial coefficients

Main article: Square well potential: virial coefficients

References

1. J. A. Barker and D. Henderson "Perturbation Theory and Equation of State for Fluids: The Square-Well Potential", Journal of Chemical Physics 47 pp. 2856-2861 (1967)
2. Elisabeth Schöll-Paschinger, Ana Laura Benavides and Ramon Castañeda-Priego "Vapor-liquid equilibrium and critical behavior of the square-well fluid of variable range: A theoretical study", Journal of Chemical Physics 123 234513 (2005)
3. R. López-Rendón, Y. Reyes and P. Orea "Thermodynamic properties of short-range square well fluid", Journal of Chemical Physics 125 084508 (2006)