Mayer f-function

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The Mayer f-function, or f-bond is defined as:

where

Diagrammatically the Mayer f-function is written as

Hard sphere model

For the hard sphere model the Mayer f-function becomes:

where is the hard sphere diameter.

References

  1. Joseph E. Mayer "Contribution to Statistical Mechanics", Journal of Chemical Physics 10 pp. 629-643 (1942)