Editing Mayer f-function
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The '''Mayer ''f''-function''', or ''f-bond'' is defined as | The '''Mayer ''f''-function''', or ''f-bond'' is defined as: | ||
:<math>f_{12}=f({\mathbf r}_{12}) | :<math>f_{12}=f({\mathbf r}_{12})= \exp\left(-\frac{\Phi_{12}(r)}{k_BT}\right) -1 </math> | ||
where | where | ||
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* <math>T</math> is the [[temperature]]. | * <math>T</math> is the [[temperature]]. | ||
* <math>\Phi_{12}(r)</math> is the [[intermolecular pair potential]]. | * <math>\Phi_{12}(r)</math> is the [[intermolecular pair potential]]. | ||
[[Cluster diagrams | Diagrammatically]] the Mayer ''f''-function is written as | [[Cluster diagrams | Diagrammatically]] the Mayer ''f''-function is written as | ||
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where <math>\sigma</math> is the hard sphere diameter. | where <math>\sigma</math> is the hard sphere diameter. | ||
==References== | ==References== | ||
#[http://dx.doi.org/10.1063/1.1723631 Joseph E. Mayer "Contribution to Statistical Mechanics", Journal of Chemical Physics '''10''' pp. 629-643 (1942)] | #[http://dx.doi.org/10.1063/1.1723631 Joseph E. Mayer "Contribution to Statistical Mechanics", Journal of Chemical Physics '''10''' pp. 629-643 (1942)] | ||
[[Category: Statistical mechanics]] | [[Category: Statistical mechanics]] | ||
[[Category: Integral equations]] | [[Category: Integral equations]] | ||