Ideal gas Helmholtz energy function: Difference between revisions

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m (New page: From equations :<math>Q_{NVT}=\frac{1}{N!} \left( \frac{V}{\Lambda^{3}}\right)^N</math> and :<math>A=-k_B T \ln Q_{NVT}</math> one has :<math>A=-k_BT\left(\ln \frac{1}{N!} + N\ln\frac{V}...)
 
mNo edit summary
Line 2: Line 2:
:<math>Q_{NVT}=\frac{1}{N!} \left( \frac{V}{\Lambda^{3}}\right)^N</math>
:<math>Q_{NVT}=\frac{1}{N!} \left( \frac{V}{\Lambda^{3}}\right)^N</math>
and  
and  
:<math>A=-k_B T \ln Q_{NVT}</math>
:<math>\left.A\right.=-k_B T \ln Q_{NVT}</math>
one has
one has
:<math>A=-k_BT\left(\ln \frac{1}{N!} + N\ln\frac{V}{\Lambda^{3}}\right)</math>
:<math>A=-k_BT\left(\ln \frac{1}{N!} + N\ln\frac{V}{\Lambda^{3}}\right)</math>

Revision as of 16:20, 21 February 2007

From equations

and

one has

using Stirling's approximation

one arrives at