Editing Heat capacity
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In a classical system the excess heat capacity for a monatomic fluid is given by subtracting the [[Ideal gas: Energy |ideal internal energy]] (which is kinetic in nature) | In a classical system the excess heat capacity for a monatomic fluid is given by subtracting the [[Ideal gas: Energy |ideal internal energy]] (which is kinetic in nature) | ||
:<math>C_v^{ex} = C_v - \frac{3}{2} | :<math>C_v^{ex} = C_v - \frac{3}{2}Nk_BT</math> | ||
in other words the excess heat capacity is associated with the component of the internal energy due to the intermolecular potential, and for that reason it is also known as the ''configurational'' heat capacity. Given that the excess internal energy for a pair potential is given by (Eq. 2.5.20 in <ref>J-P. Hansen and I. R. McDonald "Theory of Simple Liquids", Academic Press (2006) (Third Edition) ISBN 0-12-370535-5 </ref>): | in other words the excess heat capacity is associated with the component of the internal energy due to the intermolecular potential, and for that reason it is also known as the ''configurational'' heat capacity. Given that the excess internal energy for a pair potential is given by (Eq. 2.5.20 in <ref>J-P. Hansen and I. R. McDonald "Theory of Simple Liquids", Academic Press (2006) (Third Edition) ISBN 0-12-370535-5 </ref>): |