Gibbs energy function: Difference between revisions

From SklogWiki
Jump to navigation Jump to search
m (New page: Definition: :<math>\left.G\right.=A+pV</math> :<math>\left.G\right.=U-TS+pV</math> Taking the total derivative :<math>\left.dG\right.=dU-TdS-SdT+pdV+Vdp</math> but from equation \ref...)
 
mNo edit summary
Line 10: Line 10:
:<math>\left.dG\right.=dU-TdS-SdT+pdV+Vdp</math>
:<math>\left.dG\right.=dU-TdS-SdT+pdV+Vdp</math>


but from equation \ref{secondlaw} we obtain
From the [[Second law of thermodynamics]]  one obtains


:<math>\left.dG\right.=TdS -pdV-TdS-SdT+pdV+Vdp</math>
:<math>\left.dG\right.=TdS -pdV-TdS-SdT+pdV+Vdp</math>

Revision as of 19:10, 22 February 2007

Definition:


Taking the total derivative

From the Second law of thermodynamics one obtains

thus one arrives at


For G(T,p) we have the following total differential


Good for $NpT$