Cluster integrals: Difference between revisions
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In an [[ideal gas]] there are no intermolecular interactions. However, in an imperfect or real gas, this is not so, and the | |||
[[second virial coefficient]] is other than zero. Mayer and Mayer developed a theoretical treatment of the | |||
[[Virial equation of state |virial coefficients]] in terms of '''cluster integrals'''. | |||
The simplest cluster is that consisting of a single molecule, not bound to any other. | The simplest cluster is that consisting of a single molecule, not bound to any other. | ||
A cluster of three specified molecules, ''i'', ''j'' and ''k'' may be formed in any of four ways: | A cluster of three specified molecules, ''i'', ''j'' and ''k'' may be formed in any of four ways: | ||
Revision as of 15:12, 31 July 2007
In an ideal gas there are no intermolecular interactions. However, in an imperfect or real gas, this is not so, and the second virial coefficient is other than zero. Mayer and Mayer developed a theoretical treatment of the virial coefficients in terms of cluster integrals.
The simplest cluster is that consisting of a single molecule, not bound to any other. A cluster of three specified molecules, i, j and k may be formed in any of four ways:
See also
References
- Joseph Edward Mayer and Maria Goeppert Mayer "Statistical Mechanics" John Wiley and Sons (1940)