Classical thermodynamics
Definition:
where is the Gibbs energy function, leading to
where is the Helmholtz energy function,
is the Boltzmann constant, is the pressure, is the temperature and
is the volume.
Statistical mechanics
The chemical potential is the derivative of the Helmholtz energy function with respect to the
number of particles
where is the partition function for a fluid of
identical particles
and is the
configurational integral
Kirkwood charging formula
The Kirkwood charging formula is given by [1]
where is the intermolecular pair potential and is the pair correlation function.
See also
References
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