Legendre transform

The Legendre transform is used to perform a change of variables (see, for example, Ref. Chapter 4 section 11 Eq. 11.20 - 11.25).

If one has the function $f(x,y);$ one can write

$df={\frac {\partial f}{\partial x}}dx+{\frac {\partial f}{\partial y}}dy$

Let $p=\partial f/\partial x$, and $q=\partial f/\partial y$, thus

$df=p~dx+q~dy$

If one subtracts $d(qy)$ from $df$, one has

$df-d(qy)=p~dx+q~dy-q~dy-y~dq$

or

$d(f-qy)=p~dx-y~dq$

Defining the function $g=f-qy$ then

$dg=p~dx-y~dq$

The partial derivatives of $g$ are

${\frac {\partial g}{\partial x}}=p,~~~{\frac {\partial g}{\partial q}}=-y$.

See also

• Thermodynamic relations

References

Related reading

• Robert A. Alberty "Use of Legendre transforms in chemical thermodynamics", Pure and Applied Chemistry 73 pp. 1349-1380 (2001)