Binary phase diagrams - Revision history

Carl McBride at 16:04, 21 December 2010

2010-12-21T16:04:10Z

← Older revision		Revision as of 18:04, 21 December 2010
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	<ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.4</ref>		<ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.4</ref>
	<br>[[Image:Binary_TypeVI.png\|250px]]		<br>[[Image:Binary_TypeVI.png\|250px]]
			==See also==
			*[[Mixtures]]
	==References==		==References==
	<references/>		<references/>

Carl McBride at 16:03, 21 December 2010

2010-12-21T16:03:24Z

← Older revision		Revision as of 18:03, 21 December 2010
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	'''Binary phase diagrams'''. Studied by [[Johannis Jacobus van Laar]] using the [[Van der Waals equation of state]] <ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=697&view=image&startrow=1 J. J. van Laar "On some phenomena, which can occur in the case of partial miscibility of two liquids one of them being anomalous specially water", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 517-531 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=709&view=image&startrow=1 J. J. van Laar "On the different forms and transformations of the boundary curves in the case of partial miscibility of two liquids", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 636-646 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=2551&view=image&startrow=1 J. J. van Laar "An exact expression for the course of the spinodal curves and their of plaitpoints for all temperatures, in the case of mixture of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 646-657 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=791&view=image&startrow=1 J. J. van Laar "On the shape of the plaitpoint curves for mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''8''' pp. 33-48 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=850&view=image&startrow=1 J. J. van Laar "The shape of the spinodal and plaitpoint curves for binary mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''9''' pp. 226-235 (1906)]</ref>. The six major types of binary mixture phase diagrams, as identified by Scott and Konynenburg <ref>[http://dx.doi.org/10.1039/DF9704900087 Robert L. Scott and Peter H. van Konynenburg "Static properties of solutions. Van der Waals and related models for hydrocarbon mixtures", Discussions of the Faraday Society '''49''' pp. 87-97 (1970)]</ref><ref>[http://dx.doi.org/10.1098/rsta.1980.0266 Peter H. Van Konynenburg and Robert L. Scott "Critical Lines and Phase Equilibria in Binary Van Der Waals Mixtures", Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences '''298''' pp. 495-540 (1980)]</ref> (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by (solid lines: [[vapour pressure]] of the two components, blue dashed lines are three phase lines and red dashed lines are critical lines) <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref><ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 Figure 6.1</ref>:		'''Binary phase diagrams''' for liquids and gasses. Studied by [[Johannis Jacobus van Laar]] using the [[Van der Waals equation of state]] <ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=697&view=image&startrow=1 J. J. van Laar "On some phenomena, which can occur in the case of partial miscibility of two liquids one of them being anomalous specially water", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 517-531 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=709&view=image&startrow=1 J. J. van Laar "On the different forms and transformations of the boundary curves in the case of partial miscibility of two liquids", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 636-646 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=2551&view=image&startrow=1 J. J. van Laar "An exact expression for the course of the spinodal curves and their of plaitpoints for all temperatures, in the case of mixture of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 646-657 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=791&view=image&startrow=1 J. J. van Laar "On the shape of the plaitpoint curves for mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''8''' pp. 33-48 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=850&view=image&startrow=1 J. J. van Laar "The shape of the spinodal and plaitpoint curves for binary mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''9''' pp. 226-235 (1906)]</ref>. The six major types of binary mixture phase diagrams, as identified by Scott and Konynenburg <ref>[http://dx.doi.org/10.1039/DF9704900087 Robert L. Scott and Peter H. van Konynenburg "Static properties of solutions. Van der Waals and related models for hydrocarbon mixtures", Discussions of the Faraday Society '''49''' pp. 87-97 (1970)]</ref><ref>[http://dx.doi.org/10.1098/rsta.1980.0266 Peter H. Van Konynenburg and Robert L. Scott "Critical Lines and Phase Equilibria in Binary Van Der Waals Mixtures", Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences '''298''' pp. 495-540 (1980)]</ref> (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by (solid lines: [[vapour pressure]] of the two components, blue dashed lines are three phase lines and red dashed lines are critical lines) <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref><ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 Figure 6.1</ref>:
	==Type I==		==Type I==
	The two substances are of similar chemical types and their critical properties are comparable in magnitude <ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.3</ref>, for example, a mixture of [[argon]] and [[krypton]]		The two substances are of similar chemical types and their critical properties are comparable in magnitude <ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.3</ref>, for example, a mixture of [[argon]] and [[krypton]]

Carl McBride: Added an internal link

2010-12-21T15:18:43Z

Added an internal link

← Older revision		Revision as of 17:18, 21 December 2010
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	'''Binary phase diagrams'''. Studied by ~~J. J.~~ van Laar using the [[Van der Waals equation of state]] <ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=697&view=image&startrow=1 J. J. van Laar "On some phenomena, which can occur in the case of partial miscibility of two liquids one of them being anomalous specially water", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 517-531 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=709&view=image&startrow=1 J. J. van Laar "On the different forms and transformations of the boundary curves in the case of partial miscibility of two liquids", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 636-646 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=2551&view=image&startrow=1 J. J. van Laar "An exact expression for the course of the spinodal curves and their of plaitpoints for all temperatures, in the case of mixture of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 646-657 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=791&view=image&startrow=1 J. J. van Laar "On the shape of the plaitpoint curves for mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''8''' pp. 33-48 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=850&view=image&startrow=1 J. J. van Laar "The shape of the spinodal and plaitpoint curves for binary mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''9''' pp. 226-235 (1906)]</ref>. The six major types of binary mixture phase diagrams, as identified by Scott and Konynenburg <ref>[http://dx.doi.org/10.1039/DF9704900087 Robert L. Scott and Peter H. van Konynenburg "Static properties of solutions. Van der Waals and related models for hydrocarbon mixtures", Discussions of the Faraday Society '''49''' pp. 87-97 (1970)]</ref><ref>[http://dx.doi.org/10.1098/rsta.1980.0266 Peter H. Van Konynenburg and Robert L. Scott "Critical Lines and Phase Equilibria in Binary Van Der Waals Mixtures", Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences '''298''' pp. 495-540 (1980)]</ref> (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by (solid lines: [[vapour pressure]] of the two components, blue dashed lines are three phase lines and red dashed lines are critical lines) <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref><ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 Figure 6.1</ref>:		'''Binary phase diagrams'''. Studied by [[Johannis Jacobus van Laar]] using the [[Van der Waals equation of state]] <ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=697&view=image&startrow=1 J. J. van Laar "On some phenomena, which can occur in the case of partial miscibility of two liquids one of them being anomalous specially water", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 517-531 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=709&view=image&startrow=1 J. J. van Laar "On the different forms and transformations of the boundary curves in the case of partial miscibility of two liquids", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 636-646 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=2551&view=image&startrow=1 J. J. van Laar "An exact expression for the course of the spinodal curves and their of plaitpoints for all temperatures, in the case of mixture of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 646-657 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=791&view=image&startrow=1 J. J. van Laar "On the shape of the plaitpoint curves for mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''8''' pp. 33-48 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=850&view=image&startrow=1 J. J. van Laar "The shape of the spinodal and plaitpoint curves for binary mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''9''' pp. 226-235 (1906)]</ref>. The six major types of binary mixture phase diagrams, as identified by Scott and Konynenburg <ref>[http://dx.doi.org/10.1039/DF9704900087 Robert L. Scott and Peter H. van Konynenburg "Static properties of solutions. Van der Waals and related models for hydrocarbon mixtures", Discussions of the Faraday Society '''49''' pp. 87-97 (1970)]</ref><ref>[http://dx.doi.org/10.1098/rsta.1980.0266 Peter H. Van Konynenburg and Robert L. Scott "Critical Lines and Phase Equilibria in Binary Van Der Waals Mixtures", Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences '''298''' pp. 495-540 (1980)]</ref> (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by (solid lines: [[vapour pressure]] of the two components, blue dashed lines are three phase lines and red dashed lines are critical lines) <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref><ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 Figure 6.1</ref>:
	==Type I==		==Type I==
	The two substances are of similar chemical types and their critical properties are comparable in magnitude <ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.3</ref>, for example, a mixture of [[argon]] and [[krypton]]		The two substances are of similar chemical types and their critical properties are comparable in magnitude <ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.3</ref>, for example, a mixture of [[argon]] and [[krypton]]

Carl McBride at 14:43, 21 December 2010

2010-12-21T14:43:59Z

← Older revision		Revision as of 16:43, 21 December 2010
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	'''Binary phase diagrams'''. Studied by J. J. van Laar using the [[Van der Waals equation of state]] <ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=697&view=image&startrow=1 J. J. van Laar "On some phenomena, which can occur in the case of partial miscibility of two liquids one of them being anomalous specially water", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 517-531 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=709&view=image&startrow=1 J. J. van Laar "On the different forms and transformations of the boundary curves in the case of partial miscibility of two liquids", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 636-646 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=2551&view=image&startrow=1 J. J. van Laar "An exact expression for the course of the spinodal curves and their of plaitpoints for all temperatures, in the case of mixture of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 646-657 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=791&view=image&startrow=1 J. J. van Laar "On the shape of the plaitpoint curves for mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''8''' pp. 33-48 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=850&view=image&startrow=1 J. J. van Laar "The shape of the spinodal and plaitpoint curves for binary mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''9''' pp. 226-235 (1906)]</ref>. The six major types of binary mixture phase diagrams, as identified by Scott and Konynenburg <ref>[http://dx.doi.org/10.1039/DF9704900087 Robert L. Scott and Peter H. van Konynenburg "Static properties of solutions. Van der Waals and related models for hydrocarbon mixtures", Discussions of the Faraday Society '''49''' pp. 87-97 (1970)]</ref><ref>[http://dx.doi.org/10.1098/rsta.1980.0266 Peter H. Van Konynenburg and Robert L. Scott "Critical Lines and Phase Equilibria in Binary Van Der Waals Mixtures", Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences '''298''' pp. 495-540 (1980)]</ref> (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by (solid lines: [[vapour pressure]] of the two components, dashed lines are three phase lines and ~~dotted~~ lines are critical lines) <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref><ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 Figure 6.1</ref>:		'''Binary phase diagrams'''. Studied by J. J. van Laar using the [[Van der Waals equation of state]] <ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=697&view=image&startrow=1 J. J. van Laar "On some phenomena, which can occur in the case of partial miscibility of two liquids one of them being anomalous specially water", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 517-531 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=709&view=image&startrow=1 J. J. van Laar "On the different forms and transformations of the boundary curves in the case of partial miscibility of two liquids", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 636-646 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=2551&view=image&startrow=1 J. J. van Laar "An exact expression for the course of the spinodal curves and their of plaitpoints for all temperatures, in the case of mixture of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 646-657 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=791&view=image&startrow=1 J. J. van Laar "On the shape of the plaitpoint curves for mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''8''' pp. 33-48 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=850&view=image&startrow=1 J. J. van Laar "The shape of the spinodal and plaitpoint curves for binary mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''9''' pp. 226-235 (1906)]</ref>. The six major types of binary mixture phase diagrams, as identified by Scott and Konynenburg <ref>[http://dx.doi.org/10.1039/DF9704900087 Robert L. Scott and Peter H. van Konynenburg "Static properties of solutions. Van der Waals and related models for hydrocarbon mixtures", Discussions of the Faraday Society '''49''' pp. 87-97 (1970)]</ref><ref>[http://dx.doi.org/10.1098/rsta.1980.0266 Peter H. Van Konynenburg and Robert L. Scott "Critical Lines and Phase Equilibria in Binary Van Der Waals Mixtures", Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences '''298''' pp. 495-540 (1980)]</ref> (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by (solid lines: [[vapour pressure]] of the two components, blue dashed lines are three phase lines and red dashed lines are critical lines) <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref><ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 Figure 6.1</ref>:
	==Type I==		==Type I==
	The two substances are of similar chemical types and their critical properties are comparable in magnitude <ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.3</ref>, for example, a mixture of [[argon]] and [[krypton]]		The two substances are of similar chemical types and their critical properties are comparable in magnitude <ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.3</ref>, for example, a mixture of [[argon]] and [[krypton]]

Carl McBride at 14:10, 21 December 2010

2010-12-21T14:10:39Z

← Older revision		Revision as of 16:10, 21 December 2010
Line 1:		Line 1:
	'''Binary phase diagrams'''. Studied by J. J. van Laar using the [[Van der Waals equation of state]] <ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=697&view=image&startrow=1 J. J. van Laar "On some phenomena, which can occur in the case of partial miscibility of two liquids one of them being anomalous specially water", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 517-531 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=709&view=image&startrow=1 J. J. van Laar "On the different forms and transformations of the boundary curves in the case of partial miscibility of two liquids", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 636-646 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=2551&view=image&startrow=1 J. J. van Laar "An exact expression for the course of the spinodal curves and their of plaitpoints for all temperatures, in the case of mixture of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 646-657 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=791&view=image&startrow=1 J. J. van Laar "On the shape of the plaitpoint curves for mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''8''' pp. 33-48 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=850&view=image&startrow=1 J. J. van Laar "The shape of the spinodal and plaitpoint curves for binary mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''9''' pp. 226-235 (1906)]</ref>. The six major types of binary mixture phase diagrams (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by (solid lines: [[vapour pressure]] of the two components, dashed lines are three phase lines and dotted lines are critical lines) <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref><ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 Figure 6.1</ref>:		'''Binary phase diagrams'''. Studied by J. J. van Laar using the [[Van der Waals equation of state]] <ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=697&view=image&startrow=1 J. J. van Laar "On some phenomena, which can occur in the case of partial miscibility of two liquids one of them being anomalous specially water", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 517-531 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=709&view=image&startrow=1 J. J. van Laar "On the different forms and transformations of the boundary curves in the case of partial miscibility of two liquids", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 636-646 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=2551&view=image&startrow=1 J. J. van Laar "An exact expression for the course of the spinodal curves and their of plaitpoints for all temperatures, in the case of mixture of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 646-657 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=791&view=image&startrow=1 J. J. van Laar "On the shape of the plaitpoint curves for mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''8''' pp. 33-48 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=850&view=image&startrow=1 J. J. van Laar "The shape of the spinodal and plaitpoint curves for binary mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''9''' pp. 226-235 (1906)]</ref>. The six major types of binary mixture phase diagrams, as identified by Scott and Konynenburg <ref>[http://dx.doi.org/10.1039/DF9704900087 Robert L. Scott and Peter H. van Konynenburg "Static properties of solutions. Van der Waals and related models for hydrocarbon mixtures", Discussions of the Faraday Society '''49''' pp. 87-97 (1970)]</ref><ref>[http://dx.doi.org/10.1098/rsta.1980.0266 Peter H. Van Konynenburg and Robert L. Scott "Critical Lines and Phase Equilibria in Binary Van Der Waals Mixtures", Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences '''298''' pp. 495-540 (1980)]</ref> (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by (solid lines: [[vapour pressure]] of the two components, dashed lines are three phase lines and dotted lines are critical lines) <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref><ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 Figure 6.1</ref>:
	==Type I==		==Type I==
	The two substances are of similar chemical types and their critical properties are comparable in magnitude <ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.3</ref>, for example, a mixture of [[argon]] and [[krypton]]		The two substances are of similar chemical types and their critical properties are comparable in magnitude <ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.3</ref>, for example, a mixture of [[argon]] and [[krypton]]
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	<references/>		<references/>
	;Related reading		;Related reading
	*[http://dx.doi.org/10.1098/rsta.1980.0266 P. H. Van Konynenburg and R. L. Scott "Critical Lines and Phase Equilibria in Binary Van Der Waals Mixtures", Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences '''298''' pp. 495-540 (1980)]


	[[category: mixtures]]		[[category: mixtures]]

Carl McBride: Added references to Rowlinson and Swinton book

2010-12-21T14:02:39Z

Added references to Rowlinson and Swinton book

← Older revision		Revision as of 16:02, 21 December 2010
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	'''Binary phase diagrams'''. Studied by J. J. van Laar using the [[Van der Waals equation of state]] <ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=697&view=image&startrow=1 J. J. van Laar "On some phenomena, which can occur in the case of partial miscibility of two liquids one of them being anomalous specially water", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 517-531 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=709&view=image&startrow=1 J. J. van Laar "On the different forms and transformations of the boundary curves in the case of partial miscibility of two liquids", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 636-646 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=2551&view=image&startrow=1 J. J. van Laar "An exact expression for the course of the spinodal curves and their of plaitpoints for all temperatures, in the case of mixture of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 646-657 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=791&view=image&startrow=1 J. J. van Laar "On the shape of the plaitpoint curves for mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''8''' pp. 33-48 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=850&view=image&startrow=1 J. J. van Laar "The shape of the spinodal and plaitpoint curves for binary mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''9''' pp. 226-235 (1906)]</ref>. The six major types of binary mixture phase diagrams (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by (solid lines: [[vapour pressure]] of the two components, dashed lines are three phase lines and dotted lines are critical lines) <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref>:		'''Binary phase diagrams'''. Studied by J. J. van Laar using the [[Van der Waals equation of state]] <ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=697&view=image&startrow=1 J. J. van Laar "On some phenomena, which can occur in the case of partial miscibility of two liquids one of them being anomalous specially water", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 517-531 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=709&view=image&startrow=1 J. J. van Laar "On the different forms and transformations of the boundary curves in the case of partial miscibility of two liquids", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 636-646 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=2551&view=image&startrow=1 J. J. van Laar "An exact expression for the course of the spinodal curves and their of plaitpoints for all temperatures, in the case of mixture of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 646-657 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=791&view=image&startrow=1 J. J. van Laar "On the shape of the plaitpoint curves for mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''8''' pp. 33-48 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=850&view=image&startrow=1 J. J. van Laar "The shape of the spinodal and plaitpoint curves for binary mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''9''' pp. 226-235 (1906)]</ref>. The six major types of binary mixture phase diagrams (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by (solid lines: [[vapour pressure]] of the two components, dashed lines are three phase lines and dotted lines are critical lines) <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref><ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 Figure 6.1</ref>:
	==Type I==		==Type I==
	[[Image:Binary_TypeI.png\|250px]]		The two substances are of similar chemical types and their critical properties are comparable in magnitude <ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.3</ref>, for example, a mixture of [[argon]] and [[krypton]]
			<br>[[Image:Binary_TypeI.png\|250px]]
	==Type II==		==Type II==
	[[Image:Binary_TypeII.png\|250px]]		<ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.4</ref>
			<br>[[Image:Binary_TypeII.png\|250px]]
	==Type III==		==Type III==
	[[Image:Binary_TypeIII.png\|250px]]		<ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.5</ref>
			<br>[[Image:Binary_TypeIII.png\|250px]]
	==Type IV==		==Type IV==
	[[Image:Binary_TypeIV.png\|250px]]		<ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.6</ref>
			<br>[[Image:Binary_TypeIV.png\|250px]]
	==Type V==		==Type V==
	[[Image:Binary_TypeV.png\|250px]]		<ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.6</ref>
			<br>[[Image:Binary_TypeV.png\|250px]]
	==Type VI==		==Type VI==
	[[Image:Binary_TypeVI.png\|250px]]		<ref>J. S. Rowlinson and F. L. Swinton "Liquids and Liquid Mixtures", 3rd edition (1982) ISBN 0408241934 § 6.4</ref>
			<br>[[Image:Binary_TypeVI.png\|250px]]
	==References==		==References==
	<references/>		<references/>

Carl McBride at 13:39, 21 December 2010

2010-12-21T13:39:49Z

← Older revision		Revision as of 15:39, 21 December 2010
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	'''Binary phase diagrams''' ~~studied~~ by J. J. van Laar using the [[Van der Waals equation of state]] <ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=697&view=image&startrow=1 J. J. van Laar "On some phenomena, which can occur in the case of partial miscibility of two liquids one of them being anomalous specially water", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 517-531 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=709&view=image&startrow=1 J. J. van Laar "On the different forms and transformations of the boundary curves in the case of partial miscibility of two liquids", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 636-646 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=2551&view=image&startrow=1 J. J. van Laar "An exact expression for the course of the spinodal curves and their of plaitpoints for all temperatures, in the case of mixture of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 646-657 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=791&view=image&startrow=1 J. J. van Laar "On the shape of the plaitpoint curves for mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''8''' pp. 33-48 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=850&view=image&startrow=1 J. J. van Laar "The shape of the spinodal and plaitpoint curves for binary mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''9''' pp. 226-235 (1906)]</ref>. The six major types of binary mixture phase diagrams (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref>:		'''Binary phase diagrams'''. Studied by J. J. van Laar using the [[Van der Waals equation of state]] <ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=697&view=image&startrow=1 J. J. van Laar "On some phenomena, which can occur in the case of partial miscibility of two liquids one of them being anomalous specially water", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 517-531 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=709&view=image&startrow=1 J. J. van Laar "On the different forms and transformations of the boundary curves in the case of partial miscibility of two liquids", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 636-646 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=2551&view=image&startrow=1 J. J. van Laar "An exact expression for the course of the spinodal curves and their of plaitpoints for all temperatures, in the case of mixture of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 646-657 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=791&view=image&startrow=1 J. J. van Laar "On the shape of the plaitpoint curves for mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''8''' pp. 33-48 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=850&view=image&startrow=1 J. J. van Laar "The shape of the spinodal and plaitpoint curves for binary mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''9''' pp. 226-235 (1906)]</ref>. The six major types of binary mixture phase diagrams (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by (solid lines: [[vapour pressure]] of the two components, dashed lines are three phase lines and dotted lines are critical lines) <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref>:
	==Type I==		==Type I==
	[[Image:Binary_TypeI.png\|250px]]		[[Image:Binary_TypeI.png\|250px]]

Carl McBride: Added references by J. J. van Laar

2010-12-21T13:30:20Z

Added references by J. J. van Laar

← Older revision		Revision as of 15:30, 21 December 2010
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	'''Binary phase diagrams'''. The six major types of binary mixture phase diagrams (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref>:		'''Binary phase diagrams''' studied by J. J. van Laar using the [[Van der Waals equation of state]] <ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=697&view=image&startrow=1 J. J. van Laar "On some phenomena, which can occur in the case of partial miscibility of two liquids one of them being anomalous specially water", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 517-531 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=709&view=image&startrow=1 J. J. van Laar "On the different forms and transformations of the boundary curves in the case of partial miscibility of two liquids", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 636-646 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=2551&view=image&startrow=1 J. J. van Laar "An exact expression for the course of the spinodal curves and their of plaitpoints for all temperatures, in the case of mixture of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''7''' pp. 646-657 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=791&view=image&startrow=1 J. J. van Laar "On the shape of the plaitpoint curves for mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''8''' pp. 33-48 (1905)]</ref><ref>[http://www.digitallibrary.nl/proceedings/search/detail.cfm?pubid=850&view=image&startrow=1 J. J. van Laar "The shape of the spinodal and plaitpoint curves for binary mixtures of normal substances", Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen '''9''' pp. 226-235 (1906)]</ref>. The six major types of binary mixture phase diagrams (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref>:
	==Type I==		==Type I==
	[[Image:Binary_TypeI.png\|250px]]		[[Image:Binary_TypeI.png\|250px]]

Carl McBride: Added image links

2010-12-21T11:55:23Z

Added image links

← Older revision		Revision as of 13:55, 21 December 2010
Line 1:		Line 1:
	'''Binary phase diagrams'''. The six major types of binary mixture phase diagrams (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref>:		'''Binary phase diagrams'''. The six major types of binary mixture phase diagrams (in the [[Phase diagrams: Pressure-temperature plane \| pressure-temperature plane]]) are given by <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref>:
	==Type I==		==Type I==
			[[Image:Binary_TypeI.png\|250px]]
	==Type II==		==Type II==
			[[Image:Binary_TypeII.png\|250px]]
	==Type III==		==Type III==
			[[Image:Binary_TypeIII.png\|250px]]
	==Type IV==		==Type IV==
			[[Image:Binary_TypeIV.png\|250px]]
	==Type V==		==Type V==
			[[Image:Binary_TypeV.png\|250px]]
	==Type VI==		==Type VI==
			[[Image:Binary_TypeVI.png\|250px]]
	==References==		==References==
	<references/>		<references/>

Carl McBride: Started page

2010-12-21T11:29:04Z

Started page

New page

'''Binary phase diagrams'''. The six major types of binary mixture phase diagrams (in the [[Phase diagrams: Pressure-temperature plane | pressure-temperature plane]]) are given by <ref>[http://dx.doi.org/10.1021/ar00135a004 Robert L. Scott "Models for phase equilibria in fluid mixtures", Accounts of Chemical Research '''20''' pp. 97-107 (1987)]</ref>:
==Type I==
==Type II==
==Type III==
==Type IV==
==Type V==
==Type VI==
==References==
<references/>
;Related reading
*[http://dx.doi.org/10.1098/rsta.1980.0266 P. H. Van Konynenburg and R. L. Scott "Critical Lines and Phase Equilibria in Binary Van Der Waals Mixtures", Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences '''298''' pp. 495-540 (1980)]

[[category: mixtures]]